IPHAB Toxins

Rhodes et al.,, 2010: Rhodes, L.; Smith, K.; Selwood, A. I.; McNabb, P.; van Ginkel, R.; Holland, P. T.; Munday, R. Production of pinnatoxins by a peridinoid dinoflagellate isolated from Northland, New Zealand. Harmful Algae 2010, 9 (4), 384-389, Article. DOI: 10.1016/j.hal.2010.01.008.
Rhodes et al.,, 2011: Rhodes, L., Smith, K., Selwood, A., McNabb, P., Munday, R., Suda, S., Molenaar, S., Hallegraeff, G., 2011. Dinoflagellate Vulcanodinium rugosum identified as the causative organism of pinnatoxins in Australia, New Zealand and Japan. Phycologia 50(6), 624-628.
Hess et al.,, 2013: Hess, P., Abadie, E., Herve, F., Berteaux, T., Sechet, V., Araoz, R., Molgo, J., Zakarian, A., Sibat, M., Rundberget, T., Miles, C.O., Amzil, Z., 2013. Pinnatoxin G is responsible for atypical toxicity in mussels (Mytilus galloprovincialis) and clams (Venerupis decussata) from Ingril, a French Mediterranean lagoon. Toxicon 75, 16-26.
Nézan & Chomérat, 2011: Nézan, E., Chomérat, N., 2011. Vulcanodinium rugosum gen. et sp. nov. (Dinophyceae), un nouveau dinoflagellé marin de la côte méditerraneenne française. Cryptogamie, Algologie 32(1), 3-18.

Structure
Formula: C42H63NO7
Exact mono-isotopic mass: 693.46045
Molfile: see other Chemfiles
Alternative molfiles: n/a
SMILES: C[C@@H](CN=C1CCCC(C[C@@H]2CC[C@](O)(C)[C@](O2)(O3)CC[C@@]3(O4)CCC[C@@H]4C5)=C)[C@@H](C)C[C@@]61[C@]([C@@H]7O[C@]85C[C@@H](C)[C@@H](O)[C@H]7O8)([H])C=C(C=C)CC6
Alternative SMILES: n/a
InChi key: HHJLLPFQZCUZAJ-HZOPFIBCSA-N
Alternative InChi keys: n/a
InChi: InChI=1S/C42H63NO7/c1-7-30-13-17-39-22-27(3)29(5)25-43-34(39)12-8-10-26(2)20-31-14-16-38(6,45)42(47-31)19-18-40(50-42)15-9-11-32(46-40)24-41-23-28(4)35(44)37(49-41)36(48-41)33(39)21-30/h7,21,27-29,31-33,35-37,44-45H,1-2,8-20,22-25H2,3-6H3/t27-,28+,29-,31-,32+,33+,35+,36-,37+,38+,39+,40+,41+,42+/m0/s1
Alternative InChis
Spectra available: True
Chem files: chemfiles/PnTX-G.mol chemfiles/PnTX-G.cdxml

Certified

True

Certified links

National Research Council Canada
PnTX-G: Certified Calibration Solution for Pinnatoxin-G P. McCarron, S. Giddings, S. Crain, K. Thomas and M. Quilliam National Research Council of Canada CRM-PnTX-G is a certified calibration solution designed for analytical method development and accurate quantitation of PnTX-G. The concentration of CRM-PnTX-G makes it suitable for preparing a dilution series for calibration of liquid chromatography (LC) and liquid chromatography-mass spectrometry (LC-MS) instrumentation, as well as for spiking shellfish control samples for recovery experiments.

Non certified reference material

Unknown

ANSES,, 2019: ANSES, 2019. Opinion of the French Agency for Food, Environmental and Occupational Health & Safety on the assessment of the health risks associated with pinnatoxins in shellfish. French Agency for Food, Environmental and Occupational Health & Safety, Maisons-Alfort, France.
EFSA,, 2010: EFSA, 2010. Marine biotoxins in shellfish - Cyclic Imines (spirolides, gymnodimines, pinnatoxins and pteriatoxins), Scientific Opinion of the Panel on Contaminants in the Food chain; adopted on 5 July 2010. EFSA Journal 8(6), 1-39.

Pinnatoxin G